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Zep Heavy-Duty Citrus Degreaser, Pump Spray, Professional Use-12/11/2017-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Cleaner and degreaser.Structure such as solid, liquid, aerosol etc.
Form: pump sprayDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 2024600 Galleria Parkway SE, Suite 1500
Atlanta GA 30339
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 068439-46-3 -- 3.0-5.0 -- -- -- -- 094266-47-4 -- 1.0-5.0 -- -- -- -- 068439-57-6 -- 1.0-5.0 -- -- -- -- 007732-18-5 -- -- -- -- -- 005989-27-5 -- Xn, Xi, N -- -- -- -- 000128-37-0 -- -- -- -- -- 029911-28-2 -- -- -- -- -- 000112-34-5 -- Xi -- -- -- -- 000064-02-8 -- -- -- -- -- 061790-12-3 -- -- -- -- -- 000141-43-5 -- Xn, C -- -- -- -- 888888-07-4 -- -- -- -- -- 001310-73-2 -- C -- -- -- -- 888888-03-6 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)C9-11 Pareth-3
068439-46-3
500-446-03.0-5.0 No H319 P280, P305+P351+P338, P310 No No Citrus extract
094266-47-4
304-454-31.0-5.0 No -- -- -- No No Sodium olefin sulfonate
068439-57-6
931-534-01.0-5.0 No H315, H318 P264, P280, P302+P352, P305+P351+P338, P362, P310 No No Water
007732-18-5
231-791-2-- No -- -- -- No No d-Limonene
005989-27-5
227-813-5-- No H226, H315, H317, H410 -- No No 2,6-Di-t-butyl-p-cresol (BHT)
000128-37-0
204-881-4-- No H410 -- No No Dipropylene glycol monobutyl ether
029911-28-2
249-951-5-- No -- -- -- No No Diethylene glycol monobutyl ether
000112-34-5
203-961-6-- No H319 P264, P280, P305+P351+P338, P337+P313 No No Tetrasodium EDTA
000064-02-8
200-573-9-- No H332, H302, H318 -- No No Tall oil fatty acid(s)
061790-12-3
263-107-3-- No -- -- -- No No Monoethanolamine (MEA)
000141-43-5
205-483-3-- No H302, H312, H332, H314, H335, H412 P273, P501 No No C12-16 Alcohols Ethoxylated 7EO
888888-07-4
---- No -- -- -- No No Sodium hydroxide
001310-73-2
215-185-5-- No H290, H314, H315, H319 P260, P280, P303+P361+P353, P305+P351+P338, P310 No No Liquitint Brilliant Orange Dye
888888-03-6
---- No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH290 : May be corrosive to metalsH302 : Harmful if swallowedH312 : Harmful in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH332 : Harmful if inhaledH335 : May cause respiratory irritationH410 : Very toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P260 : Do not breathe dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP362 : Take off contaminated clothing and wash before reuseP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP337+P313 : Get medical advice/attentionP501 : Dispose of contents/container to
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : IrritantGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :December 11, 2017 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3 2 0 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels11.0-12.0 -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
Danger. Combustible liquid. May cause an allergic skin reaction. Causes serious eye damage.
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ eye protection/ face protection.
Response
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
Store in a well-ventilated place. Keep cool.
Disposal
Dispose of contents/container in accordance with local regulation. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Combustible liquid. May cause an allergic skin reaction. Causes serious eye damage.
Potential Health Effects
Eye Contact: Causes serious eye damage.
Skin Contact: May cause an allergic skin reaction.
Inhalation: No information.
Ingested: No information. -
Chronic health effects
From SDS:
No data. -
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1 percent is identified as probable, possible or confirmed human carcinogen by IARC.OSHA: No component of this product present at levels greater than or equal to 0.1 percent is identified as a carcinogen or potential carcinogen by OSHA.NTP: No component of this product present at levels greater than or equal to 0.1 percent is identified as a known or anticipated carcinogen by NTP. -
Handling information
Do not breathe vapours/dust. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Do not store near acids. -
Disposal information
Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. -
California Prop. 65 Warning
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm
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First Aid
Eye Contact: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. Continue rinsing eyes during transport to hospital. Remove contact lenses.Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Skin Contact: Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. If skin irritation persists, call a physician.Inhalation: If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physicianIngestion: Keep respiratory tract clear. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
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